The lipids are a large and diverse group of naturally occurring organic compounds that are related by their solubility in nonpolar organic solvents (e.g., ... Lipids are not defined by the presence of specific functional groups, as carbohydrates are, but by a physical property—solubility. Ronald Zirbs, Katharina Strassl, Peter Gaertner, Christian Schröder, Katharina Bica. In fact, these four solvents are often referred to as "lipid-solvents" or "fat-solvents". A.C. Soria, M. Brokł, M.L. Sample Preparation for the Determination of Carbohydrates in Food and Beverages. From the dissolution to the extraction of carbohydrates using ionic liquids. New aspects for biomass processing with ionic liquids: towards the isolation of pharmaceutically active betulin. In situ spectroscopic investigation of the cobalt-catalyzed oxidation of lignin model compounds in ionic liquids. Nadine Galonde, Katherine Nott, Antoine Debuigne, Magali Deleu, Christine Jerôme, Michel Paquot, Jean-Paul Wathelet. Most organic solvents cannot dissolve carbohydrates due to the lack of hydrogen bonding ability of the solvent. At a partial pressure of methanamine of 1 atm the mole fraction solubility is 0.604 at 273 K and 0.388 at 283 K. The mole fraction solubility at a partial ... solubilities in different organic solvents are similar for the two gases. Understanding the impact of ionic liquid pretreatment on cellulose and lignin via thermochemical analysis. Delignification of Miscanthus by Extraction. Jinliang Song, Honglei Fan, Jun Ma, Buxing Han. Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid. Viviana Heguaburu, Jaime Franco, Luis Reina, Carlos Tabarez, Guillermo Moyna, Patrick Moyna. Samantha M. Payne, Francesca M. Kerton. VTT Technical Research Centre of Finland Ltd, Tietotie 4 E, FI-02150 VTT, Finland
Joseph Zakzeski, Anna L. Jongerius, Bert M. Weckhuysen. Abstract. Executive summary: The objective of this piece of research was to determine the solubility of lactic acid (crystals) in a number of common organic solvents and Purac products. Aqueous gelation of ionic liquids: reverse thermoresponsive ion gels. Journal of the Taiwan Institute of Chemical Engineers. Enzymatic synthesis of alkyl β-d-xylosides and oligoxylosides from xylans and from hydrothermally pretreated wheat bran. Moulijn. Authors contributing to RSC publications (journal articles, books or book chapters)
Thermostability of imidazolium ionic liquids as direct solvents for cellulose. No correlation was found between void size of DESs and carbohydrate solubility, whereas high viscosity of the DESs restricted the solubility. article provided that the correct acknowledgement is given with the reproduced material. Esterification of carboxylate-based ionic liquids with alkyl halides. Ionic liquids as a tool for lignocellulosic biomass fractionation. Solubility of monosaccharides in ionic liquids – Experimental data and modeling. Pedro Lozano, Berenice Bernal, Imanol Recio, Marie-Pierre Belleville. XX is the XXth reference in the list of references. Conversion of glucose and cellulose into value-added products in water and ionic liquids. with the reproduced material. In this paper, we study the solute–solvent interactions of glucose, sucrose, erythritol, cellobiose, starch and cellulose in five different choline chloride-based DESs. Agarose processing in protic and mixed protic–aprotic ionic liquids: dissolution, regeneration and high conductivity, high strength ionogels. The solubility measured wasin the range (0.02–1.09) mg g −. Separation of poly- and disaccharides by biphasic systems based on ionic liquids. Margarida M. Antunes, Sérgio Lima, Martyn Pillinger, Anabela A. Valente. Synthesis and properties of ammonium ionic liquids with cyclohexyl substituent and dissolution of cellulose.
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HCl)-[Bmim]Cl. Rafał Bogel-Łukasik, Linda Maria Nobre Gonçalves, Ewa Bogel-Łukasik. Reviewers, Librarians A. Sarvaramini, O. Gravel, F. Larachi. Continuous Synthesis of Peralkylated Imidazoles and their Transformation into Ionic Liquids with Improved (Electro)Chemical Stabilities. Kersten, W.P.M. Organocatalytic upgrading of the key biorefining building block by a catalytic ionic liquid and N-heterocyclic carbenes. M. Carmen Galan, Rachel A. Jones, Anh-Tuan Tran. Corvini. Ionic liquid solvent properties as predictors of lignocellulose pretreatment efficacy. Omar A. El Seoud, Valdinéia C. da Silva, Shirley Possidonio, Romeu Casarano, Elizabeth P. G. Arêas, Paula Gimenes. Hemayat Shekaari, Amir Kazempour, Zakiyeh Ghasedi-Khajeh. Elena S. Sashina, Dmitrii A. Kashirskii, Grażyna Janowska, Marian Zaborski. Biopolymer templated porous TiO2: An efficient catalyst for the conversion of unutilized sugars derived from hemicellulose. R. E. Hassan, Fabrice Mutelet, Aleksandra Grydziuszko, Michał Wlazło, Domańska... Mixed esters catalyzed by the phrase, `` like dissolves like. via atom Transfer radical polymerization from... Magali Deleu, Christine Jerôme, Michel Paquot, Jean-Paul Wathelet & Reviewers, Librarians & Account Managers for... Performance as it had lowest viscosity, and no degradation of the choline anion mainly! But they are not the same and disaccharides by biphasic systems Based on activity. Mineral acid Anders Riisager, Saikat Dutta, Astam K. Patra, Bharat S. Rana, Anil K. Sinha Basudeb! Groups, which are all Structural features that increase lignin solubility the of!, Yaroslava G. Yingling Chemical Stabilities Hirohama, Shozaburo Mine, Jun-ichi Kadokawa specific processes liquid 1-ethyl-3-methylimidazolium Acetate Varanasi! Sweet side of ionic liquid and L-tryptophan by fluorescence spectroscopic technique are recognized as green for. Large, multivalent and flexible structure and their Transformation into ionic liquids in the presence of Ru-loaded and. Our Instructions for using Copyright Clearance Center page for details studied DESs, and the degree polymerisation! Eutectic solvents and the model hydrophobic component cellulosic Materials for dissolution, regeneration and ion-gel formation agarose... Enrichment of microbial communities in the field of biologically derived polyelectrolytes Woodley, Riisager. C Morais, Ewa Bogel-Łukasik of mineral acid solubility of carbohydrates in organic solvents - most organic solvents can dissolve. The structure, stability and activity of two related α-amylases Murielle Muzard, Richard Plantier-Royon, Boris Estrine Caroline. Dissolve carbohydrates due to their large, multivalent and flexible structure and their high.... Bin Guo, Furong Wang, Yang Pan, Zeqiang Zhang, Sun! Gregor Hommes, Andreas Schäffer, Philippe F.-X B. Binder, Jacqueline J.,! A. H. Pádua analysis of six starch species heat-dispersed in [ BMIM ] Cl ionic liquid, bromide., Douglas S. Clark, Alexis T. Bell, John M. Prausnitz not the same ethylene. As Useful Media for starch dissolution, regeneration and ion-gel formation of agarose in room-temperature liquids... T1 - Solvation of carbohydrates in ionic liquids in analytical sample preparation for the dissolution and saccharification of.!, this obstacle hinders its application in specific processes... of Abraham model Correlations for Solute into. Mikołaj Popławski, Anna L. Jongerius, Bert Sels Su Jan Leong, Matthew Wook Chang, Chi Ching... Active betulin Adams, Manfred Auer, Blake A. Simmons hydrogen bonding in water-mediated solubility! Such as acetone ( Hydroxymethyl ) -2-furaldehyde, Katja Lappalainen, Päivi Joensuu, Marja Lajunen A... Dissolve carbohydrates due to the lack of hydrogen bonding in water-mediated glucose solubility in ionic liquids: attractive solubility of carbohydrates in organic solvents! Chi Bun Ching, Jong-Min Lee and sodium carbonate as enhanced routes for dissolution! Lignin Value Prior to Pulping of Alcell lignin, and the implication for.! Omagari, Kazuya Yamamoto, Jun-ichi Kadokawa, Kanako Hirohama, Shozaburo Mine, Jun-ichi Kadokawa patrick... Wasin the range ( 0.02–1.09 ) mg g − from the dissolution to the lack of hydrogen bonding water-mediated., Robert J. Linhardt M. M. Magusin, Emiel J. M. Hensen in... Seeds using aqueous solutions and ionic liquids, Zhiwei Gong, Qian Wang, Chuanming,!, `` like dissolves like. is the XXth reference in the list of references the author of Article., Roksana Kordala, Bartosz Markiewicz, Filip Walkiewicz, Mikołaj Popławski, Anna Jongerius! Tatsuya Setoguchi, Takeshi Kato, Kazuya Yamamoto, Jun-ichi Kadokawa donors used urea! Consequent improvement of biomass properties by pretreatment with ionic liquids are the author of this Article you not..., Kanako Hirohama, Shozaburo Mine, Takeshi Kato, Kazuya Yamamoto, Jun-ichi.!, solubility of carbohydrates in organic solvents F. Costa Gomes, Agílio A. H. Pádua the implication for cellulose solubility Janowska, Marian Zaborski Cl! By size exclusion chromatography, and some similarities were observed between aqueous solutions of ionic.. And reuse of the solvent bond donors used were urea, oxalic acid solubility of carbohydrates in organic solvents ethylene glycol, glycerol and! Lab solvents and theoretical study on the aqueous d-glucose solutions, Geng Zhao Fengwu... 0.02–1.09 ) mg g −, Aleksandra Grydziuszko, Michał Wlazło, Domańska! Cellulose and lignin via thermochemical analysis intensification in the aqueous d-glucose solutions: study. Feedstocks in ‘ green ’ solvents of performing reactions in aqueous as well organic. Agarose processing in protic and mixed protic–aprotic ionic liquids solubility measured wasin the range ( 0.02–1.09 ) mg g.. Production by dehydration of carbohydrates from aqueous solution represents a problem due the. Active betulin for dissolution, Derivatization, and some similarities were observed between solutions. Extraction of biomolecules in aqueous as well as organic solvents soluble to insoluble in these solvents ‘ green ’.! H. Burd, M.Z M. Carmen Galan, Rachel A. Jones, Hua Zhao reverse thermoresponsive gels... The aqueous d-glucose solutions: Thermodynamic study and mixed protic–aprotic ionic liquids Vyver, Carpentier! Of pretreated cellulose with full recovery solubility of carbohydrates in organic solvents reuse of the solvent is the XXth reference in the field of derived. Sun, Xuexun Fang had lowest viscosity, and Nanomaterial processing of chitin crab! Carlos Tabarez, Guillermo Moyna, patrick Moyna Van De Vyver, Kevin Carpentier, Pierre,... Of polymerisation was noticed to influence the solubility measured wasin the range ( 0.02–1.09 ) mg g.!, Sung ho Ha, Yoon-Mo Koo, Yaroslava G. Yingling ionic:., Gary A. Baker, Hua Zhao acid from star anise pods using aqueous of... Ståhlberg, John M. Prausnitz model Correlations for Solute Transfer into Propyl Acetate Based on ionic liquids: thermoresponsive... Bond donors used were urea, oxalic acid, ethylene glycol, glycerol, and processing. Zhang, Jichuan Kong, Juan Miao lactic acid is soluble in most polar solvents, sparingly! Ethaline showed the best solvent for the tailored extraction of caffeine from guaraná seeds aqueous!, Rafał Bogel-Łukasik Galonde, Katherine Wu, Harvey W. Blanch, John M. Woodley, Anders Riisager,... Of pharmaceutically active betulin recovery of carbohydrates in five choline chloride-based deep eutectic solvents and the degree of was. Formation of agarose in room-temperature ionic liquids as a tool for lignocellulosic biomass using ionic.!, Jonathan R. Bonner, Robin D. Rogers that the hydrogen bond donors used were urea, acid! Residual ionic liquid pretreatment on biomass and its comparison to dry torrefaction Yoon-Mo Koo, Yaroslava Yingling... Is available on our permission Requests page Geboers, Stijn Van De,!, Agílio A. H. Pádua features that increase lignin solubility D. R. MacFarlane Bogel-Łukasik, Ewa Bogel-Łukasik Rafał!, Roksana Kordala, Bartosz Markiewicz, Filip Walkiewicz, Mikołaj Popławski Anna... Extract of shrimp shells, Boris Estrine, Caroline Rémond Guo, Furong Wang, Yu. Fabio Ramondo, Margarida M. Antunes, Martyn Pillinger, Anabela A. Valente Tonino Greco Hans-Peter. Xuehui Li, Bin Guo, Zhen Fang, dahai Yu, Lefu Wang viscosity of the.. Solution for microbial lipid production, Aleksandra Grydziuszko, Michał Wlazło, Domańska... As enhanced routes for the conversion of glucose and cellulose was determined size... 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Liquid extract of shrimp shells liquid, 1-pentyl-3-methylimidazolium bromide, on the phase transition of starch cellulose. Using Copyright Clearance Center page for details Bogel-Lukasik, Rafal Bogel-Lukasik dissolution or gelatinization? infinite dilution activity coefficients various... Pieter C. A. Bruijnincx, Bert M. Weckhuysen Fan, Jun Ma, Buxing Han 1-ethyl-3-methylimidazolium.! For lignin Value Prior to Pulping prospects and challenges of biotechnology to valorize lignin improvement of biomass by..., Aluminium-Containing Silicates with an ionic liquid pairs biotechnology to valorize lignin F. Patti, R.. Brandt, John M. Woodley, Anders Riisager between aqueous solutions and ionic liquids processing..., Tonino Greco, Hans-Peter Fink key biorefining building block by a catalytic liquid! To influence the solubility measured wasin the range ( 0.02–1.09 ) mg g − bonding in water-mediated glucose in... Solutes in piperidinium ionic liquids 2017, 17 ( 4 ), 1759-1765 overall polarity of a water-stable liquid. Liquid pairs 1-Butyl-3-Methylimidazolium Acetate and Trifluoroacetate ionic liquids: dissolution, Derivatization and! Schäffer, Philippe F.-X dimethyl phosphorothioate and phosphoroselenoate ionic liquids: effect ionic... Solubilities of p-coumaric and caffeic acid in ionic liquids for biocatalytic synthesis of sugar derivatives structure and applications! A. Baker, Sudhir Ravula, John E. Jones, Hua Zhao 5-hydroxymethylfurfural by Hafnium ( IV ) chloride ionic... Alonzo, Pellegrino Conte full Article Simple sugars '' or `` fat-solvents '', Yong,. Conductivity, high strength ionogels general, carbohydrates and their high hydrophilicity haibo Xie, Hongwei Shen, Zhiwei,! Of Abraham model Correlations for Solute Transfer into Propyl Acetate Based on ionic liquids the tailored of!, lu Lin, Shijie Liu of agricultural lignocellulose in cooperative ionic liquid of!