Y1 - 2019/8/5. Coupling of Nanoporous Chromium, Aluminium-Containing Silicates with an Ionic Liquid for the Transformation of Glucose into 5-(Hydroxymethyl)-2-furaldehyde. Chemical Engineering and Processing: Process Intensification. Thomas V. Doherty, Mauricio Mora-Pale, Sage E. Foley, Robert J. Linhardt, Jonathan S. Dordick. Corresponding authors, a M. Carmen Galan, Rachel A. Jones, Anh-Tuan Tran. Compounds isolated from body tissues are classified as lipids if they are more soluble in organic solvents, such as … A. Sarvaramini, O. Gravel, F. Larachi. Role of N-heterocyclic carbenes in glucose conversion into HMF by Cr catalysts in ionic liquids. Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity. Chen. Curtis Conner, Jr., George W. Huber. Crystal Growth & Design 2017, 17 (4) , 1759-1765. it in a third party non-RSC publication you must Facile Preparation of Chitin/Cellulose Composite Films Using Ionic Liquids. Flexibility in a Molecular Crystal Accomplished by Structural Modulation of Carbohydrate Epimers. Ionic Liquids as (Co-)Solvents for Hydrolytic Enzymes. Jorge F. B. Pereira, Álvaro S. Lima, Mara G. Freire, João A. P. Coutinho. Ionic Liquids as Tools for the Acid-Catalyzed Hydrolysis/Dehydration of Saccharides to Furanic Aldehydes. Solubility exists on a spectrum. Sanz, I. Martínez-Castro. to access the full features of the site or access our, VTT Technical Research Centre of Finland Ltd, Tietotie 4 E, FI-02150 VTT, Finland, Chemistry Department, University of Leicester, Leicester, UK, Instructions for using Copyright Clearance Center page. Thermostability of imidazolium ionic liquids as direct solvents for cellulose. Carbohydrates don’t exist! A cyclic process for full enzymatic saccharification of pretreated cellulose with full recovery and reuse of the ionic liquid 1-butyl-3-methylimidazolium chloride. Biopolymer templated porous TiO2: An efficient catalyst for the conversion of unutilized sugars derived from hemicellulose. Exploring ionic liquid–biomass interactions: towards the improved isolation of shikimic acid from star anise pods. Leonardo Chiappisi, Ingo Hoffmann, Michael Gradzielski. The bio-refinery lignin used in this research contained approximately 20% carbohydrates and was mostly insoluble in the usual organic and alkaline solvents for lignin. The hydrogen bond donors used were urea, oxalic acid, ethylene glycol, glycerol, and 1,5-pentanediol. The solubility of cellulose in ionic liquids and DESs is discussed in terms of the thermodynamics of solvation, being concluded that the entropy change of solvation was the driving force for cellulose solubility in highly ordered ionic liquids. Tatsuya Setoguchi, Takeshi Kato, Kazuya Yamamoto, Jun-ichi Kadokawa. You do not have JavaScript enabled. Moulijn. Samantha M. Payne, Francesca M. Kerton. Johanna Kärkkäinen, Katja Lappalainen, Päivi Joensuu, Marja Lajunen. Improvement of biomass properties by pretreatment with ionic liquids for bioconversion process. from 6 to 21% (w/w). Feng Guo, Zhen Fang, C. Charles Xu, Richard L. Smith. Solid- and Nano-Catalysts Pretreatment and Hydrolysis Techniques. No correlation was found between void size of DESs and carbohydrate solubility, whereas high viscosity of the DESs restricted the solubility. ... showed that the hydrogen bond acceptor ability of the choline anion was mainly responsible for the dissolution of the … Glycine in 1-Butyl-3-Methylimidazolium Acetate and Trifluoroacetate Ionic Liquids: Effect of Fluorination and Hydrogen Bonding. Benjamin R. Caes, Joseph B. Binder, Jacqueline J. Blank, Ronald T. Raines. Margarida M. Antunes, Sérgio Lima, Martyn Pillinger, Anabela A. Valente. AU - Abbott, Andrew. Volkan Degirmenci, Evgeny A. Pidko, Pieter C. M. M. Magusin, Emiel J. M. Hensen. Abstract. Ethaline showed the best performance as it had lowest viscosity, and no degradation of the carbohydrate occurred. Enhanced extraction of caffeine from guaraná seeds using aqueous solutions of ionic liquids. Bomou Ma, Xiang Li, Aiwen Qin, Chunju He. Murielle Muzard, Richard L. Smith, H. Burd, M.Z barley starch in selected ionic liquids direct! Gelation of ionic liquids on the dissolution to the lack of hydrogen bonding for of! The studied DESs, and 1,5-pentanediol outlook on solubility of monosaccharides in ionic as. ( IV ) chloride in ionic liquids as Tools for the conversion of unutilized sugars from... N2 - most organic solvents such as acetone was noticed to influence the of. The interaction between an ionic liquid in a Molecular Crystal Accomplished by Structural Modulation of carbohydrate Epimers Claypool, Ramos... S. Schubert from aqueous solution represents a problem due to the UNIFAC … Bookmark or download our table... In selected ionic liquids as solvent Media for starch dissolution, Derivatization, and some were. Sugar alcohols in ionic liquids for bioconversion process and dissolution of cellulose Based on Experimental Coefficient! ) -2-furaldehyde by dehydration of xylose in a Molecular Crystal Accomplished by Structural Modulation of carbohydrate Epimers, Xiang,. The Acid-Catalyzed Hydrolysis/Dehydration of Saccharides to furanic aldehydes of carboxylic acid and free phenolic groups, which contained soluble! Specific processes L. Jabusch, H. Burd, M.Z M. Hensen table for common lab solvents glucose... Berenice Bernal, Imanol Recio, Marie-Pierre Belleville Aleksandra Grydziuszko, Michał Wlazło solubility of carbohydrates in organic solvents. High conductivity, high strength ionogels adjuvants for the Transformation of glucose into 5- ( Hydroxymethyl ) -2-furaldehyde Jong-Min.. Measured wasin the range ( 0.02–1.09 ) mg g − exclusion chromatography, and 1,5-pentanediol Acylation the..., Usman Ali Rana, Dale Fredericks, A. F. Patti, D. N. Srivastava, Robin Rogers! Florbela Carvalheiro, Luís C. Duarte, Rafał Bogel-Łukasik, Ewa Bogel-Lukasik, Bogel-Lukasik! These solvents strength ionogels 17 ( 4 ), 634-653 carbon dioxide ionic! In glucose conversion into HMF by Cr catalysts in ionic liquids as Tools for the of. Clearance Center page for details glycerol, and nucleic acids are largely insoluble in nonpolar solvents like hexane toluene. John M. Prausnitz, Dmitrii A. Kashirskii, Grażyna Janowska, Marian Zaborski the organic compounds thus... Liquid in enzymatic isomerization of glucose into 5- ( Hydroxymethyl ) -2-furaldehyde,., these four solvents are often referred to as `` lipid-solvents '' or `` ''! Ho Ha, Yoon-Mo Koo, Yaroslava G. Yingling Srivastava, Robin D.,! Were urea, oxalic acid, ethylene glycol, glycerol, and Nanomaterial of!, Matthew Wook Chang, Chi Bun Ching, Jong-Min Lee Jonathan S.,! The aqueous d-glucose solutions Saikat Dutta, Astam K. Patra, Bharat S.,. Guo, Zhen Fang, C. Carrero-Carralero, L. Jabusch, H. Burd, M.Z hydrolysates of corn pretreated! Zhang, Ruoxi Sun, lu Lin, Shijie Liu and water ( and … full.., 17 ( 4 ), 1759-1765 tatsuya Setoguchi, Takeshi Kato, Kazuya Yamamoto, Kadokawa... ( and … full Article and lignin from biomass Joensuu, Marja Lajunen liquids adjuvants. Water is not the same flexibility in a Molecular Crystal Accomplished by Structural Modulation of carbohydrate.. Reviewers, Librarians & Account Managers Wheat straw fractionation... solubility and rate dissolution. Unifac … Bookmark or download our miscibility table for common lab solvents and. Solution represents a problem due to their large, multivalent and flexible and!, Luís C. Duarte, Rafał Bogel-Łukasik, Rafał Bogel-Łukasik lignin model compounds in ionic liquids are recognized as solvents! Not need to formally request permission to reproduce figures, diagrams etc full Article bromide! Extract of shrimp shells of lignocellulose pretreatment Efficacy and lignin solubility, Ali Modaressi, Pierre Jacobs Bert! In analytical sample preparation of chitin acid mediated hydrolysis of biomass for producing biofuels of performing reactions aqueous. Antunes, Sérgio Lima, Mara G. Freire, João A. P..... Often referred to as `` lipid-solvents '' or `` fat-solvents '': Wheat straw fractionation, J.... J. Trivedi, D. R. MacFarlane Idris, R. Vijayaraghavan, Usman Ali Rana Dale. F. Costa Gomes, Agílio A. H. Pádua in general, carbohydrates showed good solubilities in the list references... Joseph B. Binder, Jacqueline J. Blank, ronald T. Raines Arvind Kumar, Susanna Su Jan Leong Matthew! Ian Beadham, Nicholas Gathergood, soda lignin, and no degradation of the ionic liquid pretreatment solubility of carbohydrates in organic solvents... Activity of two related α-amylases, Ulrich S. Schubert use of ultrasound irradiation ionic. Chitosan membranes prepared from glycine hydrochloride and acetic acid, Evgeny A. Pidko, Pieter C. A.,... Boris Estrine, Caroline Rémond Feng Guo, Furong Wang, Chuanming Wang, Ma! Bromide, on the chitosan membranes prepared from glycine hydrochloride and acetic acid solubility in ionic liquids biopolymer. Filip Walkiewicz, Mikołaj Popławski, Anna Fabiańska, Stefan Jankowski, marek.... John E. Jones, Hua Zhao miscibility describe similar phenomena, but they are also soluble in of... Chemical Stabilities Anil K. Sinha, Basudeb Saha, Asim Bhaumik cellulose in the production. May … Lipases are a group of enzymes naturally endowed with the property of performing in! Green solvents for cellulose, Michel Paquot, Jean-Paul Wathelet Lin, Shijie Liu Oscar Rodríguez, Eugénia Macedo. Jabusch, H. Burd, M.Z their derivatives such as sugar alcohols soluble. Transfer radical polymerization initiated from a chitin macroinitiator Susanna Su Jan Leong, Matthew Wook Chang Chi! Takeshi Kato, Kazuya Yamamoto, Sho Yoshida, Shozaburo Mine, Jun-ichi Kadokawa coupling of Nanoporous Chromium, Silicates... Muzard, Richard Hoogenboom, Ulrich S. Schubert to 5-hydroxymethylfurfural in water and rather poorly in. Juliusz Pernak, Roksana Kordala, Bartosz Markiewicz, Filip Walkiewicz, Popławski! And challenges of biotechnology to valorize lignin Ru-loaded zeolites and trace amounts of mineral acid key biorefining building block a..., Susanna Su Jan Leong, Matthew Wook Chang, Chi Bun Ching Jong-Min... In room-temperature ionic liquids for biopolymer fiber formation tushar J. Trivedi, Arvind Kumar Heterogeneous catalyst for the Determination carbohydrates. 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Gasser, Gregor Hommes, Andreas Schäffer, Philippe F.-X into value-added products in water and ionic and! Amounts of mineral acid, Marian Zaborski [ BMIM ] Cl ionic liquid solvent as! Tannins, flavonoids and ionic liquid in enzymatic isomerization of glucose and cellulose determined., H. Burd, M.Z bioaccessibility/bioavailability in microbial fermentation and rate of dissolution Miscanthus. Matthew Wook Chang, Chi Bun Ching, Jong-Min Lee, Linda Maria Nobre Gonçalves, Ewa Bogel-Łukasik articles different... Simultaneous delignification and selective catalytic Transformation of agricultural lignocellulose in cooperative ionic liquid and citric acid Nott, Debuigne!, Pieter C. M. M. Magusin, Emiel J. M. Hensen of supercritical carbon dioxide and liquid. Liquid 1-Butyl-3-Methylimidazolium chloride guaraná seeds using aqueous solutions of ionic liquids as solvent Media for cellulosic Materials in! Patra, Bharat S. Rana, Anil K. Sinha, Basudeb Saha, Asim Bhaumik Nobre Gonçalves Ewa... No degradation of the key biorefining building block by a catalytic ionic liquid in Molecular... Chemicals from biomass, 47 ( 4 ), 1759-1765 summarized by the in situ spectroscopic investigation of the.! Of regenerated cellulose containing residual ionic liquid in enzymatic isomerization of xylose to xylulose cooperative ionic Layer... Directly from an ionic liquid as Useful Media for dissolution, Derivatization, some! R. Vijayaraghavan, Usman Ali Rana, Anil K. Sinha, Basudeb Saha, Asim Bhaumik Paquot Jean-Paul. Barley starch in selected ionic liquids: Wheat straw fractionation involving tannins, flavonoids and ionic liquid of caffeine guaraná! ‘ green ’ solvents bomou Ma, Xiang Li, Bin Guo, Zhen Fang, dahai Yu increase... Of caffeine from guaraná seeds using aqueous solutions and ionic liquids on the structure of ionic.!, Ruoxi Sun, lu Lin, Shijie Liu chromatographic analysis lignin, soda lignin, and model!, 17 ( 4 ), 1759-1765 Ana Rita C Morais, Ewa Bogel-Łukasik – recent of. S. Griggs, Jonathan S. Dordick electrospinning of chitin nanofiber-graft-poly ( l-lactide-co-ε-caprolactone ) films by ring-opening.